2.Our time together
1. Glass applications & Processing
2. Glass properties
3. Glass laboratory
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3.Art, Science, & Technology
“It is misleading to divide human actions into ‘art,’ ‘science,’ or ‘technology,’ for the artist has something of the scientist in him, and the engineer of both, and the very meaning of these terms varies with time so that analysis can easily degenerate into semantics.”
“Nearly everyone believes, falsely, that technology is applied science…. Technology is more closely related to art than to science…because the technologist, like the artist, must work with many unanalyzable complexities.
“Historically, the first discovery of useful materials, machines, or processes has almost always been in the decorative arts, and was not done for a perceived practical purpose. Necessity is not the mother of invention – only of improvement.”
Smith, C.S., A Search for Structure. MIT Press, Cambridge (1981), 191, 323.
Martin Demaine: MIT artist-in-residence
Chihuly, Columbus, OH
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4.Glass economics
Glasses account for ½ the total ceramics market (in $)
$50 billion/year
Carter, C.B. and Norton, M. G., Ceramic Materials: Science and Engineering, 2nd ed, Springer, (2013). (Fig 26.1)
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5.Glass applications & Processing
Introduction & future of glass
Antiquity of glass-making
Discovery
Ancient Near East
Egypt
Glass-blowing
RomAN
Medieval
Modern processing
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6.“A Day Made of Glass”
https://www.youtube.com/watch?v=jzLYh3j6xn8
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7.“A Day Made of Glass – Unpacked”
https://www.youtube.com/watch?v=X-GXO_urMow
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8.Realizing the vision of “Day Made of Glass”
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https://www.youtube.com/watch?v=Oxz2H9x79SY
9.Glass applications
Traditional
Bottles, containers, WINDOWS
Contemporary
OPTICAL FIBERS, DISPLAY GLASS, COVER GLASS
PHOTOCHROMIC, ANTIMICROBIAL, SELF-CLEANING
Futuristic
Grand challenges: clean energy, human health, transportation safety, efficient buildings, clean water
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11.Glassmaking – Discovery
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Glass was art before it was utilitarian
First glass made to imitate stone
c.5500-3100 BC faience (molded, glazed, fired)
c.2500-1550 BC glass core-formed beads
Slag from metal-working
Origins of glass-making unclear
Combined guild workshops
Metal slag
Faience
Glazes on pottery
Crucibles
Observation of natural glass
“William”, 12th Dynasty (MET,NY)
Faience
Glazed steatite (~4500 BC)
soapstone
Faience (~3100 BC)
quartz + natron/ash
“artificial tourquoise”
Egyptian blue (~2500 BC)
Cuprorivaite
“artificial lapis lazuli”
12.Glass of theUlu Burun (LBA)
Late bronze age glassmaking
Mesopotamian glass c.1550 BC
Egyptian glass c. 1480 BC
Amarna c. 1350 BC (Ahkenaten)
Shipwreck Kas, Turkey (~1305 BC)
Copper, tin, and cobalt glass ingots; ivory, precious stones, amber, shell, faience, gold/ copper/ bronze/ pottery vessels
Artifacts from 7 cultures
175 glass ingots:
“cobalt” and “turquoise”
Ingots match crucibles found at Amarna & Qantir Pi-ramesse, Egypt
Mycenae
Canaan
Egypt
Nubia
Cyprus
Assyria
Kassite (Babylonia)
LBA glassmaking centers
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13.glass production: Soda-Lime-Silicate
Sand
Alkali
Plant ash – Late Bronze Age Egypt
Salt-tolerant desert plants
High Mg, K impurities
Natron – Roman
From Egyptian word ntr – gives us Na
Evaporite mineral mixture, mostly Na2CO3·10H2O; impurities NaHCO3, NaCl, Na2SO4
Lime
From crucible
From shells or limestone (later)
Minor additives
Colorants, opacifiers, decolorizers
Glasswort (Salicornia)
Natron
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14.GLASS BLOWING
First blow pipe developed by “Syrians” ~ 300 BC
Brought to Rome in through trade
“Romans” were first to mix blown glass with molded glass techniques
Revolutionize glass manufacturing ($)
Above- Man blowing glass with blow pipe
Left- Blow Roman Glass Bowl
3-4 century AD (MET, NY)
Left- Cologne Cage Cup
4 century AD (Staatiliche
Collection)
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15.MEDIEVAL GLASS MAKING
Nanotechnology and color
Pane Glass from Molds
Mosaic
Applique
Complex vessels
Chartres Cathedral
(France, started 1193)
c.350 AD - England
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16.Glass and scientific innovation
Eyeglasses
to read books
Microscopes
to see microscopic life (bacteria)
Telescopes
to view astronomical bodies
Lab vessels
to hold and observe chemical reactions (without interaction with the vessel as in some metals)
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Alembic – alchemical reaction vessel
https://en.wikipedia.org/wiki/Glasses
Macfarlane, A. and G. Martin, "A World of Glass," Science, 305(5689), 1407-1408 (2004); http://dx.doi.org/10.1126/science.1093597
Rudyard Kipling, “Eye of Allah” short story, 1924
http://arstechnica.com/science/2010/06/history-of-the-telescope-draft/3/
24.Other videos and websites
Mythbusters: Glass age I
https://www.youtube.com/watch?v=12OSBJwogFc
Mythbusters: Glass age II
https://www.youtube.com/watch?v=13B5K_lAabw
CORNING: the glass age
https://www.youtube.com/watch?v=bbX9KOpDJME
http://theglassage.com/
PBS special: “How we got to now: glass”
http://video.pbs.org/video/2365351977/
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